A highly responsive, discerning, and uncomplicated technique has been devised for immobilizing reagents onto a plasticizer-free optical sensor membrane, employing polymer inclusion membranes (PIMs). This procedural strategy relies on a physical immobilization approach, specifically encapsulation, resulting in the creation of an optical sensing membrane. The responsive PIM is composed of poly(vinyl chloride) (PVC) as the fundamental polymer, Aliquat 336 as an extractant, and 4-(4 -chlorobenzylideneimino)-3-methyl-5-mercapto-1,2,4-triazole (CBIMMT) as the reagent. The optimized sensor demonstrates a linear range of 6.00-156 ng/mL for Te(IV), along with detection and quantification limits of 1.75 and 5.60 ng/mL, respectively. The sensor response time is 3.0 min, confirming its reproducibility. Effective regeneration of the sensor is achieved using a 0.2 mol/L HCl solution. The sensor membrane's selectivity is evaluated against various interfering ions, underscoring minimal interference. The sensor membrane efficacy is demonstrated through successful applications in quantifying Te(IV) levels, including natural water, chalcogenides, milk, vegetables, and soil samples.