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Simple conversion of trisodium phosphide, Na 3 P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide.

Grégoire Le CorreHansjörg Grützmacher
Published in: Dalton transactions (Cambridge, England : 2003) (2022)
A reaction of trisodium phosphide (Na 3 P) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.
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