A Nano-Sized [MnII 18 ] Metallamacrocycle as a Building Unit to Construct Stable Metal-Organic Frameworks: Effective Gas Adsorption and Magnetic Properties.
Lei ZhouBaolei ZhouShanshan CaoZheng CuiBowen QinWenliang LiXiaoying ZhangXiao-Ying ZhangPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2018)
A stable hex-type metal-organic framework (MOF, WMOF-1) was constructed by nano-sized [MnII 18 ] metallamacrocycle secondary building unit, being the one with the highest nuclearity of manganese wheel-like node in the microporous MOF. WMOF-1 displays an effective gas adsorption and the antiferromagnetic behavior.