Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes.
Helen R SharpeAna M GeerHuw E L WilliamsToby J BlundellWilliam LewisAlexander J BlakeDeborah L KaysPublished in: Chemical communications (Cambridge, England) (2018)
Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.
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