A Dimeric η1 ,η5 -Germole Dianion Bridged Titanium(III) Complex with a Multicenter Ti-Ge-Ge-Ti Bond.
Zhaowen DongOliver JankaJutta KöstersMarc SchmidtmannThomas MüllerPublished in: Angewandte Chemie (International ed. in English) (2018)
Dimeric germole dianion bridged TiIII and ZrIV complexes have been synthesized. In these complexes, the germole dianion adopts a formal η1 ,η5 coordination to the two metal centers. The bonding situation in these bridged dimers is dominated by a covalent Ge-Ge interaction that results, for example, in a strong antiferromagnetic coupling of the d1 Ti centers.