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Disentangling Structural and Electronic Properties in V 2 O 3 Thin Films: A Genuine Nonsymmetry Breaking Mott Transition.

Federico MazzolaSandeep Kumar ChaluvadiVincent PolewczykDebashis MondalJun FujiiPiu RajakMahabul IslamRegina CiancioLuisa BarbaMichele FabrizioGiorgio RossiPasquale OrgianiIvana Vobornik
Published in: Nano letters (2022)
Phase transitions are key in determining and controlling the quantum properties of correlated materials. Here, by using the combination of material synthesis and photoelectron spectroscopy, we demonstrate a genuine Mott transition undressed of any symmetry breaking side effects in the thin films of V 2 O 3 . In particular and in contrast with the bulk V 2 O 3 , we unveil the purely electronic dynamics approaching the metal-insulator transition, disentangled from the structural transformation that is prevented by the residual substrate-induced strain. On approaching the transition, the spectral signal evolves slowly over a wide temperature range, the Fermi wave-vector does not change, and the critical temperature is lower than the one reported for the bulk. Our findings are fundamental in demonstrating the universal benchmarks of a genuine nonsymmetry breaking Mott transition, extendable to a large array of correlated quantum systems, and hold promise of exploiting the metal-insulator transition by implementing V 2 O 3 thin films in devices.
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