Reaction of potassium phosphide KP(iPr)Ter with chalcogens, heteroallenes and an acyl chloride.

The reactivity of the secondary phosphide KP(iPr)Ter (1) (Ter = 2,6-bis-(2,4,6-trimethylphenyl)phenyl) toward small molecules is reported. Phosphide 1 displays distinct nucleophilic character and reacts selectively with chalcogens (S8, Sex), heteroallenes (CO2, nPrNCS), and an acyl chloride (AdCOCl) to give the corresponding dichalcogenophosphinates (2a, 3), phosphanyl formate (5), thiocarbamoylphosphane (6a), or acylphosphane (7a), respectively. Furthermore the follow-up chemistry of these products was investigated. 2a was converted to a PSPS ligand (2b) which forms a Au(I) complex (2c) with (Me2S)AuCl. Likewise, a gold complex of 7a was prepared. All species were isolated and fully characterized.