Fog collection is an effective method for addressing water shortages in arid areas. By constructing a Janus structure with asymmetric wettability on its two sides, flexible and efficient fog capture can be achieved. However, in situ detection and fog collection on a Janus surface are still challenging tasks. Herein, a novel method for producing a superhydrophilic-superhydrophobic Janus fog collector is proposed; the method utilizes a combined process in which a spatially shaped femtosecond laser treatment (superhydrophilic) is applied to one side of a copper foam and a chemical replacement reaction (superhydrophobic) is applied to the other side of the copper foam. Two configurations of the Janus structure were designed to study different water transport behaviors. Furthermore, the Au micro-nanoparticle prepared adhered to the Janus structure, indicating the effectiveness of surface-enhanced Raman spectroscopy detection. The Janus foam shows excellent sensitivity and stability on testing the fog mixed with rhodamine 6G. This surface allows for the simultaneous collection and detection of fog, which can provide insights into the preparation of Janus multifunction structures and how such structures can play a key role in the subsequent purification and usage of water resources.