Triptycene-based diiron(II) mesocates: spin-crossover in solution.

Riccardo Mobili Giovanni Preda Daniele Dondi Enrico Monzani Dhanalakshmi Vadivel Chiara Massera Dario Pasini Valeria Amendola

Published in: Chemical communications (Cambridge, England) (2024)

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T 1/2 at 243 K (Evans method).

Keyphrases

open label
room temperature
single molecule
density functional theory
randomized controlled trial
high glucose
double blind
diabetic rats
molecular dynamics
endothelial cells
ionic liquid
solid state