Study of the memory effect of PCDD/F during the combustion of several biomasses in a moving grate boiler.

The objective of this work was to study the influence of temperature on the PCDD/Fs behavior stored in biomass ashes issued from an automatic pilot-scale wood boiler. A mixture of these ashes with a dioxin mass ratio dry based of 5.9 μg kg -1 was used for thermal treatment at temperatures ranging between 200 and 500°C. First tests were carried out in a macro thermogravimetric analysis instrument while a couple of other tests were carried out in a quartz-lined crossed fixed-bed reactor. These treated ashes were afterwards analyzed and their dioxin mass ratio was determined. Results obtained from these both experiments are radically different: ashes treated in macro-TGA contain 18 times more PCDD/Fs than the initial non-treated ashes while those from the reactor have 84% less of PCDD/Fs. Ninety-one percent of stored PCDD/Fs in the initial ashes were eliminated after 1h at 400°C in crossed fixed-bed reactor. Macro-TGA experiments are a representation of what happens during the shutdown and cooling phase of the boiler, some areas reaching temperatures for which the formation of PCDD/Fs is optimal. Without cleaning the boiler, a memory effect on further tests is observed.