Rh(III)-catalyzed synthesis of amino-side-chained poly(phenylene vinylene) via C-H bond olefination.

Benfa ChuShuqi JiaTielei LiJin Zhu

Published in: Chemical communications (Cambridge, England) (2023)

A Rh(III)-catalyzed hydrazine-directed C-H olefination approach was developed for synthesizing amino-side-chained poly(phenylene vinylene) (PPV). The creation of such a divergent portfolio of PPV candidates enabled the discovery of a mega Stokes shift, high fluorescence quantum yield, and solid-state fluorescence, highlighting the great prospects of our synthetic protocol as an innovative tool.

Keyphrases

solid state
energy transfer
fluorescent probe
room temperature
single molecule
small molecule
randomized controlled trial
high throughput