Access to Benzocyclic Boronates via Light-Promoted Intramolecular Arylborylation of Alkenes.

Benzocyclic boronates have attracted increasing research interest in drug chemistry and organic synthesis in recent years. Herein, we report a facile access to benzocyclic boronates through photopromoted intramolecular arylborylation of allyl aryldiazonium salts. This simple protocol features a broad scope, allowing the formation of variously functionalized borates bearing dihydrobenzofuran, dihydroindene, benzothiophene, and indoline skeletons under mild and sustainable conditions.