Superwetting Oil/Water Separation Membrane Constructed from In Situ Assembled Metal-Phenolic Networks and Metal-Organic Frameworks.
Ruoxi WangXue-Ting ZhaoNing JiaLijuan ChengLifen LiuCongjie GaoPublished in: ACS applied materials & interfaces (2020)
Superwetting membranes with opposite wettability to oil and water have drawn intense attention in recent years for oil/water separation. Superhydrophilic and underwater superoleophobic membranes have shown unique advantages in the efficient treatment of oily wastewater containing oil-in-water emulsions. Facile interfacial engineering and microstructural design of the hierarchical architectures and the hydrophilic chemistry is of significance but still challenging. In this study, a hydrophilic hierarchical hybrid layer derived from metal-phenolic network (MPN)/metal-organic framework (MOF) synergy is constructed on the membrane surface via a proposed coordination-directed alternating assembly strategy. The assembly of MPN multilayers provides a hydrophilic chemical basis, and the assembly of MOF nanocrystals provides a hierarchical structural basis. Notably, the coordination interfacial interaction enables the formation of well-defined hydrophilic hierarchical architectures. The obtained membrane is thus endowed with robust superhydrophilicity, underwater superoleophobicity, and anti-oil-adhesion capability, which make it capable of highly efficient oil-water separation with high water permeance (above 6300 L/m2 h), high oil rejection (above 99.4%), and recyclable antifouling property. The high performance of the developed superwetting membrane makes it a competitive candidate for oil/water separation. Additionally, the demonstrated MPN/MOF assembly strategy may offer new prospects for the facile and versatile design of other superwetting materials.
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