Interplay between spin-crossover and luminescence in a multifunctional single crystal iron(ii) complex: towards a new generation of molecular sensors.
Bouabdellah BenaichaKhanh Van DoAymen YanguiNarsimhulu PittalaAlain LussonMouhamadou SyGuillaume BouchezHoucem FouratiCarlos J Gómez-GarcíaSmail TrikiKamel BoukheddadenPublished in: Chemical science (2019)
We present a new example of a mononuclear iron(ii) complex exhibiting a correlated spin-crossover (SCO) transition and strong fluorescence, whose coordination sphere is saturated, for the first time, by six phosphorescent ligands. The interplay between SCO and light emission properties in the thermal region of the spin transition was investigated by means of magnetic, fluorescence, optical absorption and optical microscopy measurements on a single crystal. Overall, the results show an excellent correlation between fluorescence and magnetic data of the present gradual transition, indicating an extreme sensitivity of the optical activity of the ligand to the spin state of the active iron(ii) ions. These results open the way for conceiving new prototypes of pressure and temperature sensors based on this synergy between SCO and luminescence properties. In particular, the fact that cooperative SCO material is not a prerequisite for obtaining such synergetic effects, is useful for the design of thin films or nanoparticles, in which the cooperativity is reduced, for appropriate implementation in nanosized devices to enhance the sensing properties at the nanoscale.
Keyphrases
- single molecule
- atomic force microscopy
- high speed
- energy transfer
- high resolution
- quantum dots
- room temperature
- density functional theory
- iron deficiency
- primary care
- open label
- healthcare
- molecularly imprinted
- low cost
- minimally invasive
- double blind
- light emitting
- electronic health record
- randomized controlled trial
- solid state
- peripheral blood
- placebo controlled
- cancer therapy
- quality improvement
- deep learning
- optical coherence tomography