Evolution of nanopores in hexagonal boron nitride.
Chunhui DaiDerek PoppleCong SuJi-Hoon ParkKenji WatanabeTakashi TaniguchiJing KongAlex ZettlPublished in: Communications chemistry (2023)
The engineering of atomically-precise nanopores in two-dimensional materials presents exciting opportunities for both fundamental science studies as well as applications in energy, DNA sequencing, and quantum information technologies. The exceptional chemical and thermal stability of hexagonal boron nitride (h-BN) suggest that exposed h-BN nanopores will retain their atomic structure even when subjected to extended periods of time in gas or liquid environments. Here we employ transmission electron microscopy to examine the time evolution of h-BN nanopores in vacuum and in air and find, even at room temperature, dramatic geometry changes due to atom motion and edge contamination adsorption, for timescales ranging from one hour to one week. The discovery of nanopore evolution contrasts with general expectations and has profound implications for nanopore applications of two-dimensional materials.
Keyphrases
- single molecule
- room temperature
- solid state
- electron microscopy
- ionic liquid
- molecular dynamics
- quantum dots
- small molecule
- public health
- healthcare
- blood pressure
- drinking water
- intellectual disability
- single cell
- high throughput
- health information
- mass spectrometry
- high speed
- visible light
- randomized controlled trial
- human health