High-Energy Quantum Dynamics of the 15 N + o - 14 N 14 N Rovibrational Activation and Isotope Exchange Processes.

We report full quantum reaction probabilities, computed within the framework of time-independent quantum mechanics using hyperspherical coordinates, for the 15 N + 14 N 14 N inelastic and reactive collision processes, restricted to total angular momentum J = 0, for kinetic energies up to 4.5 eV. We take advantage of the nonzero ( i = 1) nuclear spin of 14 N, leading to the existence of two nuclear spin isomers of 14 N 14 N, namely, ortho - and para - 14 N 14 N, to restrict the study to the ortho molecular nitrogen species, with even rotational quantum number j = 0, 2, ... states. Specifically, we start with diatomic reagents ortho - 14 N 14 N in the initial rotational state j = 0. A comparison with similar works previously published by other groups using time-dependent wave packet and quasi-classical trajectory methods for the 14 N + 14 N 14 N fully symmetric collision is given. We find that reactive processes 15 N + 14 N 14 N involving atom exchange do not happen for collision energies less than 2.2 eV. Collisions at energies of around 2.0 eV are most effective for populating reactants' rovibrational states, that is, for inelastic scattering, whereas those at energies close to 5.0 eV yield a newly formed 14 N 15 N isotopologue in a wide variety of excited vibrational levels.