Switchable on-off spin-crossover properties of iron(ii) compounds by trimming intermolecular hydrogen bonds.

Na LiJin-Peng XueJing-Lin LiuYao-Yao Wang Zi-Shuo Yao Jun Tao

Published in: Dalton transactions (Cambridge, England : 2003) (2020)

Reversible single crystal-to-single crystal transformations from [FeL2(NCS)2]·3MeOH (1·3MeOH, L = 2-(anthracen-10-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) to 1 and 1·2H2O were reported, which were accompanied by on-off switching of the spin-crossover properties.

Keyphrases

room temperature
open label
density functional theory
single molecule
double blind
transition metal
randomized controlled trial
solid state
ionic liquid
molecular dynamics
iron deficiency
study protocol