Login / Signup

Copper-Catalyzed Synthesis of S-S Bond-Containing Silanols from SCBs and Trisulfide-1,1-dioxides.

Ying ChenFei WangWei-Dong RaoShusu ShenDaopeng ShengShun-Yi Wang
Published in: The Journal of organic chemistry (2023)
In this work, an efficient method for the copper-catalyzed ring-opening hydrolysis of silacyclobutanes to silanols was developed. This strategy has the advantages of friendly reaction conditions, simple operation, and good functional group compatibility. No additional additives are required in the reaction, and the S-S bond can also be introduced into the organosilanol compounds in one step. Furthermore, the success at the gram scale demonstrates the great potential of the developed protocol for practical industrial applications.
Keyphrases
  • electron transfer
  • gram negative
  • randomized controlled trial
  • heavy metals
  • wastewater treatment
  • ionic liquid
  • transition metal
  • human health
  • multidrug resistant
  • risk assessment
  • climate change