Polysiloxane-Based Liquid-like Layers for Reducing Polymer and Wax Fouling.

Surface fouling occurs when undesired matter adheres and accumulates on a surface, resulting in a decrease or loss of functionality. Polymer and wax fouling can cause costly blockages to crude oil pipelines, clog jet fuel injectors, foul chemical reaction vessels, and significantly decrease the efficiency of heat exchangers. Fouling occurs in many forms but can be segmented based on adherent size, modulus, and chemical functionality. Depending on the foulant, surface design strategies can vary greatly. Few strategies exist to prevent the buildup of wax and polymers on surfaces. In this report, we investigate the potential of highly disordered, siloxane liquid-like layers as a strategy for reducing wax and polymer deposition. In our tests, it was found that the liquid-like layers developed here were able to reduce postadsorption roughness for polymer and wax by as much as 35- and 47-fold, respectively, when compared to the control. SFG was utilized to investigate the molecular-level interfacial properties for each of the modified surfaces to help understand the antifouling mechanism. The data showed that the likely higher grafting density and a large degree of random conformational freedom at the liquid-surface interface make the developed siloxane-covered surfaces energetically unfavorable for polymer and wax accretion.