New Bio-Based Polymer Sorbents out of Terpene Compounds or Vegetable Oils: Synthesis, Properties, Analysis of Sorption Processes.

This research presents a synthesis and characterization of new bio-based polymer sorbents. Natural origin substances such as terpenes (citral, limonene, and pinene) or vegetable oils (argan, linseed, and rapeseed oils) were used as monomers, and divinylbenzene was applied as the cross-linker. The newly prepared polymers were characterized by means of ATR-FTIR, TG/DTG and titration methods (acid and iodine values), and N 2 physisorption experiments. Tests of sorption ability were carried out by a dynamic solid phase extraction method using a mixture of four phenols or single-component pharmaceutical solutions (salicylic acid, aspirin, ibuprofen, paracetamol, and ampicillin). The performed studies revealed that the terpene-based polymers possessed better-developed porous structures (420-500 m 2 /g) with more uniform pores than oil-based ones. However, the surface of the oil-based sorbents was more acidic in nature. The sorption tests showed that both the porosity and acidity of the surface significantly influenced the sorption. Recoveries of up to 90% were obtained for 2,4 dichlorophenol from C-DVB, L-DVB, and Ro-DVB. The lowest affinity to the polymers exhibited phenol (5-45%), aspirin (1-7%), and ampicillin (1-7%). A 70% recovery was achieved for ibuprofen from C-DVB. In-depth data analysis allowed the influence of various factors on the sorption process of test compounds of the studied polymers to be elucidated.