Guest-tuned spin crossover in flexible supramolecular assemblies templated by a halide (Cl-, Br- or I-).
M D DarawshehL A BarriosOlivier RoubeauS J TeatGuillem AromíPublished in: Chemical communications (Cambridge, England) (2017)
Ligand 1,3-bis(3-(pyridin-2-yl)-1H-pyrazol-5-yl)benzene, L, forms mononuclear spin crossover complexes [FeL3]2+ with pendant arms that cause them to dimerize through numerous intermolecular interactions forming supramolecular (X@[FeL3]2)3+ cations. They have the flexibility to encapsulate Cl-, Br- or I-, which allow tuning the magnetic properties, in the solid state and in solution.
Keyphrases
- solid state
- energy transfer
- room temperature
- ionic liquid
- water soluble
- density functional theory
- open label
- placebo controlled
- double blind
- single molecule
- transition metal
- peripheral blood
- molecularly imprinted
- molecular dynamics
- clinical trial
- randomized controlled trial
- quantum dots
- study protocol
- mass spectrometry
- simultaneous determination