Comprehensive Approach to the Interpretation of the Electrical Properties of Film-Forming Molecules.

This paper presents a general protocol for the interpretation of the electric surface potential of Langmuir monolayers based on a three-layer capacitor model. The measured values were correlated with the results from DFT molecular dynamics simulations, and, as a result, the local dielectric permittivities and dipole-moment components of molecules organized in the monolayer were obtained. The main advantage of the developed approach is applicability to amphiphiles of any type; irrespective of the structure of the polar head as well as the molecular organization and inclination in the surface film. The developed methodology was successively applied to an atypical surface-active compound, perfluorodecyldecane, and its derivatives containing the hydroxyl, thiol, and carboxyl moiety. The following contributions to the apparent dipole moments connected with the reorientation of water molecules and local dielectric permittivities in the vicinity of polar and apolar molecule parts, respectively, were determined: μ w /ε w = -0.85 D, ε p = 5.00, and ε a = 1.80. Moreover, the investigated perfluorodecyldecane derivatives were comprehensively characterized in terms of their surface activity, film rheology, and effective surface dissociation equilibria. The proposed methodology may be crucial for the process of the design and the preliminary characterization of molecules for sensor and material science applications.