Laser-Heat Surface Treatment of Superwetting Copper Foam for Efficient Oil-Water Separation.

Oil pollution in the ocean has been a great threaten to human health and the ecological environment, which has raised global concern. Therefore, it is of vital importance to develop simple and efficient techniques for oil-water separation. In this work, a facile and low-cost laser-heat surface treatment method was employed to fabricate superwetting copper (Cu) foam. Nanosecond laser surface texturing was first utilized to generate micro/nanostructures on the skeleton of Cu foam, which would exhibit superhydrophilicity/superoleophilicity. Subsequently, a post-process heat treatment would reduce the surface energy, thus altering the surface chemistry and the surface wettability would be converted to superhydrophobicity/superoleophilicity. With the opposite extreme wetting scenarios in terms of water and oil, the laser-heat treated Cu foam can be applied for oil-water separation and showed high separation efficiency and repeatability. This method can provide a simple and convenient avenue for oil-water separation.