Enhanced Electrorheological Response of Cellulose: A Double Effect of Modification by Urea-Terminated Silane.

As a natural polymer with abundant sources, cellulose was one of the earliest applied electrorheological (ER) materials. However, cellulose-based ER materials have not attracted much attention because of their relatively low ER effect and sensitivity to water. In this study, cellulose rods were decorated with a urea-terminated silane, 1-(3-(trimethoxysilyl) propyl) urea, after being swelled in sodium hydroxide solution. The morphologies and structures of the cellulose particles were investigated using scanning electron microscopy, Fourier-transform infrared spectroscopy and X-ray diffraction, confirming the dramatic differences of the treated cellulose particles from the pristine cellulose. Rheological behaviors of the pristine and modified cellulose particles in silicone oil were observed using a rotational rheometer. It was found that the silane-modified cellulose showed higher ER effect and higher dielectric properties than the pristine cellulose particles, which was not only related to the grafted polar molecules but may also be associated with the porous morphologies of the treated cellulose particles.