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Carbonate clumped isotope analysis (Δ47 ) of 21 carbonate standards determined via gas-source isotope-ratio mass spectrometry on four instrumental configurations using carbonate-based standardization and multiyear data sets.

Deepshikha UpadhyayJamie K LucarelliAlexandrea ArnoldRandy FloresHayley BrickerRobert N UlrichGregory JesmokLauren SantiWilliam DeflieseRobert A EagleHannah M CarrollJesse Bloom BatemanVictoria PetryshynSean J LoydJianwu TangAntra PriyadarshiBen ElliottAradhna Tripati
Published in: Rapid communications in mass spectrometry : RCM (2021)
We show that all configurations yield similar results if instrument drift is robustly characterized and validate a recent proposal for carbonate-based standardization using large multiyear data sets. Δ47 values are reported for 21 carbonate standards on both the absolute reference frame (ARF; also refered to as the Carbon Dioxide Equilibrated Scale or CDES) and the new InterCarb-Carbon Dioxide Equilibrium Scale (I-CDES) reference frame, facilitating intercomparison of data from a diversity of labs and instrument configurations and restandardization of a broad range of sample sets between 2006, when the first carbonate measurements were published, and the present.
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