Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine.
T I WittmannElvira I MusinaD B KrivolapovI A LitvinovS A KondrashovaShamil K LatypovA A KarasikO G SinyashinPublished in: Dalton transactions (Cambridge, England : 2003) (2018)
The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P4N2 is preorganized for the dicopper complex formation with the unique coordination mode in the row of P4N2 corands.
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