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Spin crossover {[Fe(atrz) 3 ](OTs) 2 } n monolith: a green synthesis approach for Robust switchable materials.

Ana Martinez-MartinezPablo AlbaceteMar García-HernándezEsther Resines-UrienDavid Fairen-JimenezJosé Sánchez Costa
Published in: Dalton transactions (Cambridge, England : 2003) (2024)
This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz) 3 ](OTs) 2 } n monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.
Keyphrases
  • room temperature
  • ionic liquid
  • randomized controlled trial
  • single molecule
  • risk assessment
  • climate change
  • molecular dynamics
  • transition metal
  • aqueous solution