Supramolecular Soft Material Enabled by Metal Coordination and Hydrogen Bonding: Stretchability, Self-Healing, Impact Resistance, 3D Printing, and Motion Monitoring.
Yunfei ZhangChangyong CaiFenfang LiShengyi DongPublished in: Small (Weinheim an der Bergstrasse, Germany) (2023)
Metal coordination can significantly improve the macroscopic performance of many materials by enhancing their dynamic features. In this study, two supramolecular interactions, Fe 3+ -carboxylic acid coordination, and structural water-induced hydrogen bonding, into an artificial polymer were introduced. Various attractive features, including flexibility and stretchability, are achieved because of the bulk state and dynamic hydrogen bonds of poly(thioctic acid-water) (poly[TA-H]). These unique features are considerably enhanced after the incorporation of Fe 3+ cations into poly[TA-H] because metal coordination increased the mobility of the poly[TA-H] chains. Thus, the poly(thioctic acid-water-metal) (poly[TA-HM]) copolymer exhibited better flexibility and stretchability. Moreover, notable underwater/low-temperature self-healing capacity is obtained via the synergistic effect of the metal and hydrogen bonding. Most of the impact energy is quickly absorbed by poly[TA-H] or poly[TA-HM] and effectively and rapidly dissipated via reversible debonding/bonding via the interactions between the metal and hydrogen. Macroscopic plastic deformation or structural failure is not observed during high-speed (50-70 m s -1 ) impact experiments or high-altitude (90 m) falling tests. Furthermore, poly[TA-HM] displayed good thermal molding properties, which enabled its processing via 3D fused deposition modeling printing. Poly[TA-HM] also showed considerable effectiveness for monitoring complicated, dynamic, and irregular biological activities owing to its highly pressure-sensitive nature.