Metal-Free Formal Inverse-Electron-Demand Diels-Alder Reaction of 1,2-Diazines with Ynamides.

Jian XueErhui GaoXiao-Na Wang Jun-Biao Chang

Published in: Organic letters (2018)

A highly effective metal-free formal inverse-electron-demand Diels-Alder reaction of 1,2-diazines with ynamides has been developed. This catalytic protocol is more environmentally friendly and allows for the construction of 2-aminonaphthalenes and 2-aminoanthracenes from 1,2-diazines and ynamides in good to high yields with wide diversity and functional group tolerance.

Keyphrases

electron transfer
randomized controlled trial
solar cells
electron microscopy
high density