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TiO 2 Nanoparticle/Polyimide Nanocomposite for Ultrahigh-Temperature Energy Storage.

Xinrui ChenWenbo ZhuJianwen ChenQing CaoYingxi ChenDengyan Hu
Published in: Nanomaterials (Basel, Switzerland) (2022)
With the development of electronic technology, there is an increasing demand for high-temperature dielectric energy storage devices based on polyimides for a wide range of applications. However, the current nanofillers/PI nanocomposites are used for energy harvesting at no more than 200 °C, which does not satisfy the applications in the oil and gas, aerospace, and power transmission industries that require an operating temperature of 250-300 °C. Therefore, we introduced a nanocomposite based on nonsolid TiO 2 nanoparticles and polyimide (PI) with high energy storage performance at an ultrahigh temperature of 300 °C. The synergy of excellent dielectric properties and a high breakdown strength endowed the nanocomposite with a low loading content of 1 wt% and a high energy storage density of 5.09 J cm -3 . Furthermore, we found that the nanocomposite could stably operate at 300 °C with an outstanding energy storage capability (2.20 J cm -3 ). Additionally, finite element simulations demonstrated that the partially hollow nanostructures of the nanofillers avoided the evolution of breakdown paths, which optimized the breakdown strength and energy storage performance of the related nanocomposites. This paper provides an avenue to broaden the application areas of PI-based nanocomposites as ultrahigh-temperature energy-storage devices.
Keyphrases
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  • high temperature
  • solid phase extraction
  • mass spectrometry
  • fatty acid
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  • metal organic framework
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