To reveal the distribution of atmospheric tritium water (HTO) vapor and provide a baseline for tritium pollution control, a subnational survey was conducted in mainland China. As the largest study on HTO vapor in China that has ever been formally reported, this study provides a macroimpression of the atmospheric HTO specific activity from March 2017 to March 2018. A total of 102 passive samplers were deployed at 34 sites in 30 provinces to determine the seasonal and spatial distributions of HTO vapor. In general, the HTO specific activity in the atmosphere ranged from lower than the minimum detectable activity (0.18 Bq·L-1) to 5.5 Bq·L-1. Spatially, the specific activity of HTO was positively correlated to the latitude and the distance to proximal coastline. Seasonally, significantly higher HTO specific activities were observed in spring and relatively lower in summer. Based on correlation analysis, the atmospheric HTO distributions were considered to be the consequence of combined factors of the stratospheric-tropospheric net mass flux, the distance from the tropopause to the ground, the fraction of air mass that originated from ocean re-evaporation and long-distance transport from high-latitude continents.