A Carbon Composite Film with Three-Dimensional Reticular Structure for Electromagnetic Interference Shielding and Electro-Photo-Thermal Conversion.

The design of flexible wearable electronic devices that can shield electromagnetic waves and work in all weather conditions remains a challenge. We present in this work a low-cost technology to prepare an ultra-thin carbon fabric-graphene (CFG) composite film with outstanding electromagnetic interference shielding effectiveness (EMI SE) and electro-photo-thermal effect. The compatibility between flexible carbon fabric skeleton and brittle pure graphene matrix empowers this CFG film with adequate flexibility. The reticular fibers and porous structures play a vital role in multiple scattering and absorption of electromagnetic waves. In the frequency range of 30-1500 MHz, the CFG film can achieve a significantly high EMI SE of about 46 dB at tiny thickness (0.182 mm) and density (1.4 g cm-3) predominantly by absorption. At low safe voltages or only in sunlight, the film can self-heat to its saturation value rapidly in 40 s. Once the electricity or light supply is stopped, it can quickly dissipate heat in tens of seconds. A combination of the EMI SE and the prominent electro-photo-thermal effect further enables such a remarkable EMI shielding film to have more potential applications for communication devices in extreme zones.