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C-H and N-H bond annulation of aryl amides with unactivated olefins by merging cobalt(iii) and photoredox catalysis.

Deepti KalsiNagaraju BarsuSagnik ChakrabartiPardeep DahiyaMagnus RuepingBasker Sundararaju
Published in: Chemical communications (Cambridge, England) (2019)
A mild, environment-friendly protocol has been developed to carry out the [4+2] annulation of aryl amides with unactivated olefins. A range of sterically and electronically diverse aryl amides and unactivated olefins were successfully employed under the developed conditions to get a variety of dihydroisoquinolinones in good-to-excellent yields.
Keyphrases
  • randomized controlled trial
  • visible light