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Structural, optical and magnetic properties of a new metal-organic Co II -based complex.

Wiem JabeurMarcus KorbMohamed HamdiMariia HolubDávid PrincíkVladimir ZelenakAntonio Sanchez-CoronillaMarwan ShalashErik CizmarHoucine Naïli
Published in: RSC advances (2024)
A mononuclear cobalt(ii) complex [C 5 H 8 N 3 ] 2 [CoCl 4 (C 5 H 7 N 3 ) 2 ] (I) was synthesized and structurally characterized. Single crystal X-ray diffraction analysis indicates that monometallic Co(ii) ions acted as coordination nodes in a distorted octahedral geometry, giving rise to a supramolecular architecture. The latter is made up of a ½ unit form composed of an anionic element [Co 0.5 Cl 2 (C 5 H 7 N 3 )] - and one 2-amino-4-methylpyrimidinium cation [C 5 H 8 N 3 ] + . The crystalline arrangement of this compound adopts the sandwich form where inorganic parts are sandwiched between the organic sheets following the [100] direction. More information regarding the structure hierarchy has been supplied based on Hirshfeld surface analysis; the X⋯H (X = N, Cl) interactions play a crucial role in stabilizing the self-assembly process of I, complemented by the intervention of π⋯π electrostatic interaction created between organic entities. Thermal analyses were carried out to study the thermal behavior process. Static magnetic measurements and ab initio calculations of compound I revealed the easy-axis anisotropy character of the central Co(ii) ion. Two-channel field-induced slow-magnetic relaxation was observed; the high-frequency channel is characterized by underbarrier relaxation with U eff = 16.5 cm -1 , and the low-frequency channel involves a direct relaxation process affected by the phonon-bottleneck effect.
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