Tailored Palladate Tunable Aryl Alkyl Ionic Liquids (TAAILs).

Felix SchroeterJohannes SoellnerThomas Strassner

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2019)

We present a new class of tunable aryl alkyl ionic liquids (TAAILs) containing different palladate counter ions. Solid-state structures for representative compounds have been obtained. Their properties are presented in comparison to those of newly synthesized and reported palladate ionic liquids with conventional counter ions. It was found that the aryl substitution pattern and the type of anion have a profound influence on the melting point. The speciation of the different anions in solution has been rationalized by DFT calculations.

Keyphrases

ionic liquid
solid state
density functional theory
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molecular dynamics
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crystal structure