Login / Signup

Anticrossing of Longitudinal and Transverse Modes in Simple Fluids.

Nikita P KryuchkovVadim V BrazhkinStanislav O Yurchenko
Published in: The journal of physical chemistry letters (2019)
If interacting modes of the same symmetry cross, they repel from each other and become hybridized. This phenomenon is called anticrossing and is well-known for mechanical oscillations, electromagnetic circuits, waveguides, metamaterials, polaritons, and phonons in crystals, but it still remains poorly understood in simple fluids. Here, we show that structural disorder and anharmonicity, governing properties of fluids, lead to the anticrossing of longitudinal and transverse modes, which is accompanied by their hybridization and strong redistribution of excitation spectra. We combined theory and simulations for noble gases to prove the reliability of mode anticrossing in simple fluids, studied here for the first time. Our results open novel prospects in understanding collective dynamics, thermodynamics, and transport phenomena in various fluids, spanning from noble gas fluids and metallic melts to strongly coupled plasmas and molecular and complex fluids.
Keyphrases
  • cross sectional
  • room temperature
  • minimally invasive
  • high frequency
  • single molecule
  • working memory
  • molecular dynamics
  • ionic liquid
  • nucleic acid