Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage.
Yiting GuRúben MartínPublished in: Angewandte Chemie (International ed. in English) (2017)
A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 -O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C-heteroatom bond formations.