One-Minute Synthesis of a Supramolecular Hydrogel from Suspension-Gel Transition and the Derived Crystalline, Elastic, and Photoactive Aerogels.
Peng MengYanan XuCheng YanJingsan XuPublished in: ACS applied materials & interfaces (2020)
Solutions or sols are commonly employed as the starting materials for the preparation of supramolecular hydrogels; however, suspension-based synthesis has been much less reported because of inhomogeneity and quick sedimentation of large particles in a suspension. Further, it remains a technical challenge to derive supramolecular aerogels directly from the parental hydrogels owing to the ease of structural collapse during water removal. Herein, we report a suspension-gel transition for the ultrafast synthesis of a new supramolecular hydrogel simply by adding AgNO3 into the aqueous suspension of cyanuric acid-melamine (CAM) aggregates. With the activation of preadded ammonia, Ag ions instantly reacted with the CAM particles, transforming into N-Ag(I)-N coordinating bonded supramolecular nanofibers; simultaneously, the suspension converted to a hydrogel without the use of polymer cross-linkers or external stimulus. Upon simple freeze-drying, a highly crystalline fibrous aerogel with a cellular network was obtained, which possessed a porosity up to 99.7% and a density as low as 4.8 mg/cm3, enabling remarkable oil uptake capacities (100 times of its weight). The supramolecular aerogel demonstrated intrinsic elasticity, which should arise from the cellular structure and elastic character of the nanofiber skeletons. Notably, the aerogel showed high compatibility to incorporate a range of external substances for further functionalization exemplified by polymeric carbon nitride (PCN, a metal-free semiconductor) included gels. The loaded PCN resulted in enhanced mechanical strength and endowed the aerogel unique photoactivity, i.e., in situ reducing Ag(I) into Ag nanoparticles upon light illumination and thus forming a plasmonic shell over the aerogel with potential applications in sensing and catalysis.
Keyphrases
- energy transfer
- quantum dots
- drug delivery
- wound healing
- hyaluronic acid
- reduced graphene oxide
- water soluble
- visible light
- room temperature
- tissue engineering
- cancer therapy
- drug release
- highly efficient
- gold nanoparticles
- drinking water
- fatty acid
- weight loss
- single molecule
- ionic liquid
- weight gain
- human health
- climate change