Palladium-Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion.

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2020)

A palladium-catalyzed annulation of acyl fluorides with norbornene is described. This study reports the first example of an annulation of acyl fluorides in the presence of a transition-metal catalyst. Polycyclic ketones are obtained from the cleavage of the C-F and C-H bonds of the acyl fluoride and the rearrangement of the carbonyl moiety by decarbonylation and CO reinsertion.

Keyphrases

transition metal
fatty acid
drinking water
room temperature
reduced graphene oxide
gold nanoparticles
carbon dioxide