Alkenyl Exchange of Allylamines via Nickel(0)-Catalyzed C-C Bond Cleavage.

Chao FanXin-Yang LvLi-Jun Xiao Jian-Hua Xie Qi-Lin Zhou

Published in: Journal of the American Chemical Society (2019)

A functional group exchange reaction between allylamines and alkenes via nickel-catalyzed C-C bond cleavage and formation was developed. This reaction provides a novel protocol, which does not require the use of unstable imine substrates, for the synthesis of allylamines, which are widely used in the production of fine chemicals, pharmaceuticals, and agrochemicals.

Keyphrases

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