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Two-Step Spin-Crossover with Three Inequivalent FeII Sites in a Two-Dimensional Hofmann-Type Coordination Polymer.

Yan MengQing-Qing ShengMd Najbul HoqueYan-Cong ChenSi-Guo WuJiri TucekRadek ZborilTao LiuZhao-Ping NiMing-Liang Tong
Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2017)
An unprecedented two-step spin-crossover behavior with the sequence of γHS =1↔γHS =3/4↔γHS =1/4 was observed in two-dimensional Hofmann type coordination polymer [Fe(isoq)2 {Ag(CN)2 }2 ] (isoq=isoquinoline), which resulted from three crystallographically inequivalent FeII sites with distinct transition temperatures.
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