Two-Step Spin-Crossover with Three Inequivalent FeII Sites in a Two-Dimensional Hofmann-Type Coordination Polymer.

Yan MengQing-Qing ShengMd Najbul HoqueYan-Cong ChenSi-Guo WuJiri TucekRadek ZborilTao LiuZhao-Ping NiMing-Liang Tong

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2017)

An unprecedented two-step spin-crossover behavior with the sequence of γHS =1↔γHS =3/4↔γHS =1/4 was observed in two-dimensional Hofmann type coordination polymer [Fe(isoq)2 {Ag(CN)2 }2 ] (isoq=isoquinoline), which resulted from three crystallographically inequivalent FeII sites with distinct transition temperatures.

Keyphrases

room temperature
open label
density functional theory
single molecule
double blind
placebo controlled
quantum dots
clinical trial
randomized controlled trial
transition metal
visible light
metal organic framework
aqueous solution