Parallel Paired Photoelectrochemical Bromination of Alkylarenes with Electrochemical Pinacol Coupling.

A paired electrochemical method for paralleling benzylic bromination of alkylarenes under irradiation with reductive pinacol coupling in a divided cell has been developed. A variety of benzyl bromides at the anode and pinacols at the cathode were obtained simultaneously in moderate-to-high faradaic efficiency. This parallel paired electrochemical protocol showed a broad substrate scope and high chemoselectivity as well as high synthetic and faradaic efficiencies.