Self-assembly of a supramolecular spin-crossover tetrahedron.

Hannah H NielsenPol VilariñoGemma RodríguezFlorian TrepardOlivier Roubeau Guillem Aromí David Aguilà

Published in: Dalton transactions (Cambridge, England : 2003) (2024)

A new mononuclear iron(II) SCO compound featuring H-bonding donor and acceptor units has been synthesized and exploited to produce a purely supramolecular switchable [Fe 4 ] tetrahedron. Magnetic and crystallographic measurements evidence a singular magnetic behavior for each of the four Fe(II) centers of the generated architecture and underscore the potential of this strategy to develop novel SCO materials.

Keyphrases

energy transfer
molecularly imprinted
water soluble
peripheral blood
open label
room temperature
single molecule
randomized controlled trial
human health
solar cells
mass spectrometry
climate change
solid phase extraction
risk assessment
iron deficiency
study protocol