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Self-assembly of a supramolecular spin-crossover tetrahedron.

Hannah H NielsenPol VilariñoGemma RodríguezFlorian TrepardOlivier RoubeauGuillem AromíDavid Aguilà
Published in: Dalton transactions (Cambridge, England : 2003) (2024)
A new mononuclear iron(II) SCO compound featuring H-bonding donor and acceptor units has been synthesized and exploited to produce a purely supramolecular switchable [Fe 4 ] tetrahedron. Magnetic and crystallographic measurements evidence a singular magnetic behavior for each of the four Fe(II) centers of the generated architecture and underscore the potential of this strategy to develop novel SCO materials.
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