Membranes Based on Aminated Graphene Oxide with High Selectivity Toward Organic Substances.

In this work, membranes based on graphene oxide, modified with oleylamine, have been prepared by a simple wet chemistry protocol without the use of complex equipment, elevated temperature, and additional reagents. The membrane material was characterized by a set of physicochemical methods: thermogravimetric analysis, Fourier transform infrared spectroscopy, X-ray diffractometry, and X-ray photoelectron spectroscopy. The prepared membranes are stable in both aqueous and organic media. The membranes have a high flux for organic substances and do not permeate water at room temperature and atmospheric pressure. The selectivity of the membranes toward organic substances increases with their thickness. The highest flux among the tested organic liquids is registered for methanol. The membranes have high selectivity toward ethanol/1-butanol and acetone/1-butanol pairs, which opens up the possibility of separating actual industrial mixtures. The membrane retains 90% of methylene blue from the alcohol solution. Our work expands the possibilities of using modified GO-based membranes in purification and filtration technologies.