Alkyl-Ethylene Amines as Effective Organic Friction Modifiers for the Boundary Lubrication Regime.

With the pursuit of fuel economy in the automotive industry, recently low-viscosity lubricant technology has been widely improved. The present work has systematically discussed a series of sulfur- and phosphorus-free organic friction modifiers (FMs)-alkyl-ethylene amines-by alkyl substitution from ethylene amines with various nitrogen-atom numbers and molecular configurations. Herein, the pin-on-flat reciprocation friction tests have exhibited that the addition of the novel alkyl-ethylene amines into base oil led to significant reductions in the friction coefficient (up to 23%). Further investigations of tribological properties at elevated temperatures demonstrated that the increased number of nitrogen atoms and the regular linear atomic arrangement contributed to an improvement of friction reduction (up to 66%) compared to the neat base oil. Notably, results of water contact angle measurement and infrared spectroscopy (IR) have provided favorable evidence that the novel FMs have adsorbed on the metal surface leading to the formation of a tribofilm, whereby the tribofilm prevented the sliding surfaces from direct asperity contact and markedly improved the tribological performance, as seen from the composition analysis of the worn surfaces by an energy-dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), and confocal Raman spectroscopy. Therefore, the present work can provide a practical reference for molecular structure design through investigation of structure-performance relations of lubricant additives.