Development and characterization of novel emulsified nanocomposite coatings incorporating different loadings of nanoclay and beeswax for paper packaging.

Paper coated with poly (vinyl alcohol) (PVA)-based films incorporating varying amounts of halloysite nanotubes (HNTs) and/or beeswax (BW) were developed. The applied PVA/HNTs nanocomposite films, PVA/BW emulsified films, and PVA/HNTs/BW emulsified nanocomposite films were characterized in terms of FTIR, TGA, DSC, and XRD analyses. The effects of HNTs and/or BW at different loadings on the functional properties of coated paper were investigated. HNTs and BW co-incorporation significantly improved the water vapor permeability of the resulting PVA/HNTs/BW coated paper samples, and reduced their Cobb 60 values, respectively, by more than 50, 24, and 18% as compared to the uncoated paper, paper coated with pristine PVA and paper coated with PVA/HNTs nanocomposite-based coatings. While increasing their contact angle values in the range of 10-20%. Likewise, HNTs and BW co-incorporation increased the mechanical strength of PVA/HNTs/BW coated paper in the range of 20.54-29.80% as compared to the uncoated paper, while increasing their flexibility up to 32.50%. Such enhancement in the functional properties of PVA/HNTs/BW coated paper is most likely due to the establishment of interactions between PVA, BW, and HNTs. Our results demonstrate the ability of PVA/HNTs/BW emulsified nanocomposite coatings to improve paper barrier and mechanical properties owing to the prominent reinforcement effects of HNTs and the good moisture-barrier properties of BW.