Block Copoly (Ester-Carbonate) Electrolytes for LiFePO 4 |Li Batteries with Stable Cycling Performance.

To address the challenges posed by the narrow oxidation decomposition potential window and the characteristic of low ionic conductivity at room temperature of solid polymer electrolytes (SPEs), carbon dioxide (CO 2 ), epichlorohydrin (PO), caprolactone (CL), and phthalic anhydride (PA) were employed in synthesizing di-block copolymer PCL-b-PPC and PCL-b-PPCP. The carbonate and ester bonds in PPC and PCL provide high electrochemical stability, while the polyether segments in PPC contribute to the high ion conductivity. To further improve the ion conductivity, we added succinonitrile as a plasticizer to the copolymer and used the copolymer to assemble lithium metal batteries (LMBs) with LiFePO 4 as the cathode. The LiFePO 4 /SPE/Li battery assembled with PCL-b-PPC electrolyte exhibited an initial discharge-specific capacity of 155.5 mAh·g -1 at 0.5 C and 60 °C. After 270 cycles, the discharge-specific capacity was 140.8 mAh·g -1 , with a capacity retention of 90.5% and an average coulombic efficiency of 99%, exhibiting excellent electrochemical performance. The study establishes the design strategies of di-block polymer electrolytes and provides a new strategy for the application of LMBs.