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Facile Preparation and Characterization of Short-Fiber and Talc Reinforced Poly(Lactic Acid) Hybrid Composite with In Situ Reactive Compatibilizers.

Phornwalan NanthananonManus SeadanSommai Pivsa-ArtHiroyuki HamadaSupakij Suttiruengwong
Published in: Materials (Basel, Switzerland) (2018)
Hybrid composites of fillers and/or fibers reinforced polymer was generally produced by masterbatch dilution technique. In this work, the simplified preparation was introduced for the large volume production of 30 wt % short-fiber and talcum reinforced polymer hybrid composite by direct feeding into twin-screw extruder. Multifunctional epoxide-based terpolymer and/or maleic anhydride were selected as in situ reactive compatibilizers. The influence of fiber and talcum ratios and in situ reactive compatibilizers on mechanical, dynamic mechanical, morphological and thermal properties of hybrid composites were investigated. The morphological results showed the strong interfacial adhesion between fiber or talcum and Poly(lactic acid) (PLA) matrix due to a better compatibility by reaction of in situ compatibilizer. The reactive PLA hybrid composite showed the higher tensile strength and the elongation at break than non-compatibilized hybrid composite without sacrificing the tensile modulus. Upon increasing the talcum contents, the modulus and storage modulus of hybrid composites were also increased while the tensile strength and elongation at break were slightly decreased compared to PLA/fiber composite. Talcum was able to induce the crystallization of PLA hybrid composites.
Keyphrases
  • lactic acid
  • reduced graphene oxide
  • staphylococcus aureus
  • cancer therapy
  • high resolution
  • gold nanoparticles
  • cystic fibrosis
  • molecular dynamics simulations
  • biofilm formation
  • cell migration
  • cell adhesion