Kenneth D Karlin

Publication Activity (10 Years)

Years Active: 2016-2024
Publications (10 Years): 41

Top Topics

Molecular Docking

Electron Transfer

Metal Organic Framework

Top Venues

Journal of the American Chemical Society

Inorganic chemistry

Angewandte Chemie (International ed. in English)

Chemical science

This page only lists publications with an associated author ORCID identifier.

Publications

Sanjib Panda, Hai Phan, Eleanor M Dunietz, Magdalene T Brueggemeyer, Pradip Kumar Hota, Maxime A Siegler, Anex Jose, Mayukh Bhadra, Edward I Solomon, Kenneth D Karlin
Intramolecular Phenolic H-Atom Abstraction by a N 3 ArOH Ligand-Supported (μ-η 2 :η 2 -Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase. Journal of the American Chemical Society 146 (22) (2024)
Pradip Kumar Hota, Sanjib Panda, Hai Phan, Bohee Kim, Maxime A Siegler, Kenneth D Karlin
Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper O 2 -Derived Peroxide Complexes. Journal of the American Chemical Society (2024)
Pradip Kumar Hota, Anex Jose, Sanjib Panda, Eleanor M Dunietz, Austin E Herzog, Laurianne Wojcik, Nicolas le Poul, Catherine Belle, Edward I Solomon, Kenneth D Karlin
Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties. Journal of the American Chemical Society 146 (19) (2024)
Pradip Kumar Hota, Anex Jose, Sanjib Panda, Eleanor M Dunietz, Austin E Herzog, Laurianne Wojcik, Nicolas le Poul, Catherine Belle, Edward I Solomon, Kenneth D Karlin
Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties. Journal of the American Chemical Society (2024)
Sanjib Panda, Hai Phan, Eleanor M Dunietz, Magdalene T Brueggemeyer, Pradip Kumar Hota, Maxime A Siegler, Anex Jose, Mayukh Bhadra, Edward I Solomon, Kenneth D Karlin
Intramolecular Phenolic H-Atom Abstraction by a N 3 ArOH Ligand-Supported (μ-η 2 :η 2 -Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase. Journal of the American Chemical Society (2024)
Sanjib Panda, Hai Phan, Eleanor M Dunietz, Magdalene T Brueggemeyer, Pradip Kumar Hota, Maxime A Siegler, Anex Jose, Mayukh Bhadra, Edward I Solomon, Kenneth D Karlin
Intramolecular Phenolic H-Atom Abstraction by a N 3 ArOH Ligand-Supported (μ-η 2 :η 2 -Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase. Journal of the American Chemical Society 146 (22) (2024)
Pradip Kumar Hota, Anex Jose, Sanjib Panda, Eleanor M Dunietz, Austin E Herzog, Laurianne Wojcik, Nicolas le Poul, Catherine Belle, Edward I Solomon, Kenneth D Karlin
Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties. Journal of the American Chemical Society 146 (19) (2024)
Pradip Kumar Hota, Sanjib Panda, Hai Phan, Bohee Kim, Maxime A Siegler, Kenneth D Karlin
Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper O 2 -Derived Peroxide Complexes. Journal of the American Chemical Society 146 (34) (2024)
Pradip Kumar Hota, Anex Jose, Sanjib Panda, Eleanor M Dunietz, Austin E Herzog, Laurianne Wojcik, Nicolas le Poul, Catherine Belle, Edward I Solomon, Kenneth D Karlin
Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties. Journal of the American Chemical Society 146 (19) (2024)
Sanjib Panda, Hai Phan, Eleanor M Dunietz, Magdalene T Brueggemeyer, Pradip Kumar Hota, Maxime A Siegler, Anex Jose, Mayukh Bhadra, Edward I Solomon, Kenneth D Karlin
Intramolecular Phenolic H-Atom Abstraction by a N 3 ArOH Ligand-Supported (μ-η 2 :η 2 -Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase. Journal of the American Chemical Society 146 (22) (2024)
Mayukh Bhadra, Therese Albert, Alicja Franke, Verena Josef, Ivana Ivanovic-Burmazovic, Marcel Swart, Pierre Moënne-Loccoz, Kenneth D Karlin
Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species En Route to a Cupric Hyponitrite Intermediate. Journal of the American Chemical Society (2023)
Mayukh Bhadra, Therese Albert, Alicja Franke, Verena Josef, Ivana Ivanovic-Burmazovic, Marcel Swart, Pierre Moënne-Loccoz, Kenneth D Karlin
Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species En Route to a Cupric Hyponitrite Intermediate. Journal of the American Chemical Society 145 (4) (2023)
Bohee Kim, Magdalene T Brueggemeyer, Wesley J Transue, Younwoo Park, Jaeheung Cho, Maxime A Siegler, Edward I Solomon, Kenneth D Karlin
Fenton-like Chemistry by a Copper(I) Complex and H 2 O 2 Relevant to Enzyme Peroxygenase C-H Hydroxylation. Journal of the American Chemical Society (2023)
Bohee Kim, Kenneth D Karlin
Ligand-Copper(I) Primary O 2 -Adducts: Design, Characterization, and Biological Significance of Cupric-Superoxides. Accounts of chemical research (2023)
Roman Davydov, Austin E Herzog, Richard J Jodts, Kenneth D Karlin, Brian M Hoffman
End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy. Journal of the American Chemical Society 144 (1) (2022)
Kenneth D Karlin, Pradip Kumar Hota, Bohee Kim
Concluding remarks: discussion on natural and artificial enzymes including synthetic models. Faraday discussions 234 (0) (2022)
Mayukh Bhadra, Wesley J Transue, Hyeongtaek Lim, Ryan E Cowley, Jung Yoon C Lee, Maxime A Siegler, Patrick Josephs, Gerald Henkel, Markus Lerch, Siegfried Schindler, Adam Neuba, Keith O Hodgson, Britt Hedman, Edward I Solomon, Kenneth D Karlin
A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity. Journal of the American Chemical Society 143 (10) (2021)
Hyun Kim, Patrick J Rogler, Savita K Sharma, Andrew W Schaefer, Edward I Solomon, Kenneth D Karlin
Ferric Heme Superoxide Reductive Transformations to Ferric Heme (Hydro)Peroxide Species: Spectroscopic Characterization and Thermodynamic Implications for H-Atom Transfer (HAT). Angewandte Chemie (International ed. in English) 60 (11) (2021)
Sarmistha Bhunia, Atanu Rana, Shabnam Hematian, Kenneth D Karlin, Abhishek Dey
Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction. Inorganic chemistry 60 (18) (2021)
Hyun Kim, Patrick J Rogler, Savita K Sharma, Andrew W Schaefer, Edward I Solomon, Kenneth D Karlin
Heme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction Reactivity. Journal of the American Chemical Society 142 (6) (2020)
Hyeongtaek Lim, Michael L Baker, Ryan E Cowley, Sunghee Kim, Mayukh Bhadra, Maxime A Siegler, Thomas Kroll, Dimosthenis Sokaras, Tsu-Chien Weng, Dalia R Biswas, David M Dooley, Kenneth D Karlin, Britt Hedman, Keith O Hodgson, Edward I Solomon
Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase. Inorganic chemistry 59 (22) (2020)
Jeffrey J Liu, Maxime A Siegler, Kenneth D Karlin, Pierre Moënne-Loccoz
Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal-Mediated Peroxynitrite Decomposition. Angewandte Chemie (International ed. in English) 58 (32) (2019)
Daniel E Diaz, Mayukh Bhadra, Kenneth D Karlin
Dimethylanilinic N-Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen Species. Inorganic chemistry 58 (20) (2019)
Melanie A Ehudin, Laura Senft, Alicja Franke, Ivana Ivanovic-Burmazovic, Kenneth D Karlin
Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c Oxidase. Journal of the American Chemical Society 141 (27) (2019)
Hyun Kim, Savita K Sharma, Andrew W Schaefer, Edward I Solomon, Kenneth D Karlin
Heme-Cu Binucleating Ligand Supports Heme/O2 and FeII-CuI/O2 Reactivity Providing High- and Low-Spin FeIII-Peroxo-CuII Complexes. Inorganic chemistry 58 (22) (2019)
Melanie A Ehudin, Leland B Gee, Sinan Sabuncu, Augustin Braun, Pierre Moënne-Loccoz, Britt Hedman, Keith O Hodgson, Edward I Solomon, Kenneth D Karlin
Tuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands. Journal of the American Chemical Society 141 (14) (2019)
Melanie A Ehudin, David A Quist, Kenneth D Karlin
Enhanced Rates of C-H Bond Cleavage by a Hydrogen-Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex. Journal of the American Chemical Society 141 (32) (2019)
Melanie A Ehudin, Andrew W Schaefer, Suzanne M Adam, David A Quist, Daniel E Diaz, Joel A Tang, Edward I Solomon, Kenneth D Karlin
Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome c oxidase inspired low-spin heme-peroxo-copper complexes. Chemical science 10 (10) (2019)
David A Quist, Melanie A Ehudin, Andrew W Schaefer, Gregory L Schneider, Edward I Solomon, Kenneth D Karlin
Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a CuII2(O2•-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H Bond. Journal of the American Chemical Society 141 (32) (2019)
Andrew W Schaefer, Melanie A Ehudin, David A Quist, Joel A Tang, Kenneth D Karlin, Edward I Solomon
Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions. Journal of the American Chemical Society 141 (12) (2019)
Gayan B Wijeratne, Mayukh Bhadra, Maxime A Siegler, Kenneth D Karlin
Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release. Journal of the American Chemical Society 141 (45) (2019)
Daniel E Diaz, David A Quist, Austin E Herzog, Andrew W Schaefer, Ioannis Kipouros, Mayukh Bhadra, Edward I Solomon, Kenneth D Karlin
Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates. Angewandte Chemie (International ed. in English) 58 (49) (2019)
Suzanne M Adam, Gayan B Wijeratne, Patrick J Rogler, Daniel E Diaz, David A Quist, Jeffrey J Liu, Kenneth D Karlin
Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function. Chemical reviews 118 (22) (2018)
Mayukh Bhadra, Jung Yoon C Lee, Ryan E Cowley, Sunghee Kim, Maxime A Siegler, Edward I Solomon, Kenneth D Karlin
Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes. Journal of the American Chemical Society 140 (29) (2018)
Seungwoo Hong, James J Yan, Deepika G Karmalkar, Kyle D Sutherlin, Jin Kim, Yong-Min Lee, Yire Goo, Pradip K Mascharak, Britt Hedman, Keith O Hodgson, Kenneth D Karlin, Edward I Solomon, Wonwoo Nam
A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterization. Chemical science 9 (34) (2018)
Isidoro López, Rui Cao, David A Quist, Kenneth D Karlin, Nicolas le Poul
Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach. Chemistry (Weinheim an der Bergstrasse, Germany) 23 (72) (2017)
Gayan B Wijeratne, Shabnam Hematian, Maxime A Siegler, Kenneth D Karlin
Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation. Journal of the American Chemical Society 139 (38) (2017)
Isaac Garcia-Bosch, Ryan E Cowley, Daniel E Díaz, Ryan L Peterson, Edward I Solomon, Kenneth D Karlin
Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2CuII2(O22-) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity. Journal of the American Chemical Society 139 (8) (2017)
Andrew W Schaefer, Matthew T Kieber-Emmons, Suzanne M Adam, Kenneth D Karlin, Edward I Solomon
Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases. Journal of the American Chemical Society 139 (23) (2017)
Savita K Sharma, Andrew W Schaefer, Hyeongtaek Lim, Hirotoshi Matsumura, Pierre Moënne-Loccoz, Britt Hedman, Keith O Hodgson, Edward I Solomon, Kenneth D Karlin
A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO(g)) with a Ferric-Superoxide Species. Journal of the American Chemical Society 139 (48) (2017)
Suzanne M Adam, Isaac Garcia-Bosch, Andrew W Schaefer, Savita K Sharma, Maxime A Siegler, Edward I Solomon, Kenneth D Karlin
Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry. Journal of the American Chemical Society 139 (1) (2016)