This study examines the use of gypsum for radiation dosimetry using Thermoluminescence (TL) and Optically Stimulated Luminescence (OSL) techniques. It is observed that gypsum preserves the information of radiation dose despite the loss of water upon heating in a laboratory. Deconvolution of the thermoluminescence glow curve suggests thermoluminescence glow peaks at 125, 150, 280, 320, and 440 °C. The glow peak at 440 °C has a minimum detectable dose of 200 mGy, and it bleaches to approximately 50% with 300 min of daylight exposure. The Blue Light Stimulated Luminescence (BLSL) comprises a slow component and is correlated to 255 °C TL glow peak. The alpha efficiency of luminescence production per unit Gy of alpha dose with respect to the beta dose for the TL glow peaks at 440 °C is calculated at 0.18 ± 0.01. For BLSL, the value is calculated at 0.15 ± 0.01. A measurement protocol for the use of gypsum for retrospective dosimetry is also presented.